Setup asks for it, and Settings › Data and storage › Storage location changes it. Give Katari a folder of its own; it fills it like this:
Katari/
autobackup/ automatic backups
downloads/ downloads
Pepper&Carrot (EN)/ comics, one folder per source
Blender Studio (EN) [anime]/ video
Project Gutenberg [book]/ books
local/ your own comics
Inside downloads/, each title has a folder of its own. After moving or deleting files there yourself, select
Settings › Advanced › Reindex downloads so Katari notices.